A report on Chemistry

An oil painting of a chemist (Ana Kansky, painted by Henrika Šantel in 1932)
Laboratory, Institute of Biochemistry, University of Cologne in Germany.
Solutions of substances in reagent bottles, including ammonium hydroxide and nitric acid, illuminated in different colors
A diagram of an atom based on the Bohr model
Standard form of the periodic table of chemical elements. The colors represent different categories of elements
Carbon dioxide (CO2), an example of a chemical compound
A ball-and-stick representation of the caffeine molecule (C8H10N4O2).
A 2-D structural formula of a benzene molecule (C6H6)
Diagram showing relationships among the phases and the terms used to describe phase changes.
An animation of the process of ionic bonding between sodium (Na) and chlorine (Cl) to form sodium chloride, or common table salt. Ionic bonding involves one atom taking valence electrons from another (as opposed to sharing, which occurs in covalent bonding)
In the methane molecule (CH4), the carbon atom shares a pair of valence electrons with each of the four hydrogen atoms. Thus, the octet rule is satisfied for C-atom (it has eight electrons in its valence shell) and the duet rule is satisfied for the H-atoms (they have two electrons in their valence shells).
Emission spectrum of iron
During chemical reactions, bonds between atoms break and form, resulting in different substances with different properties. In a blast furnace, iron oxide, a compound, reacts with carbon monoxide to form iron, one of the chemical elements, and carbon dioxide.
The crystal lattice structure of potassium chloride (KCl), a salt which is formed due to the attraction of K+ cations and Cl− anions. Note how the overall charge of the ionic compound is zero.
Hydrogen bromide exists in the gas phase as a diatomic molecule
Democritus' atomist philosophy was later adopted by Epicurus (341–270 BCE).
15th-century artistic impression of Jābir ibn Hayyān (Geber), a Perso-Arab alchemist and pioneer in organic chemistry.
Antoine-Laurent de Lavoisier is considered the "Father of Modern Chemistry".
In his periodic table, Dmitri Mendeleev predicted the existence of 7 new elements, and placed all 60 elements known at the time in their correct places.
Top: Expected results: alpha particles passing through the plum pudding model of the atom undisturbed. 
Bottom: Observed results: a small portion of the particles were deflected, indicating a small, concentrated charge.

Scientific study of the properties and behavior of matter.

- Chemistry
An oil painting of a chemist (Ana Kansky, painted by Henrika Šantel in 1932)

139 related topics with Alpha

Overall

Atoms and molecules as depicted in John Dalton's A New System of Chemical Philosophy vol. 1 (1808)

Atom

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Smallest unit of ordinary matter that forms a chemical element.

Smallest unit of ordinary matter that forms a chemical element.

Atoms and molecules as depicted in John Dalton's A New System of Chemical Philosophy vol. 1 (1808)
The Geiger–Marsden experiment:
Left: Expected results: alpha particles passing through the plum pudding model of the atom with negligible deflection.
Right: Observed results: a small portion of the particles were deflected by the concentrated positive charge of the nucleus.
The Bohr model of the atom, with an electron making instantaneous "quantum leaps" from one orbit to another with gain or loss of energy. This model of electrons in orbits is obsolete.
The binding energy needed for a nucleon to escape the nucleus, for various isotopes
A potential well, showing, according to classical mechanics, the minimum energy V(x) needed to reach each position x. Classically, a particle with energy E is constrained to a range of positions between x1 and x2.
3D views of some hydrogen-like atomic orbitals showing probability density and phase (g orbitals and higher are not shown)
This diagram shows the half-life (T½) of various isotopes with Z protons and N neutrons.
These electron's energy levels (not to scale) are sufficient for ground states of atoms up to cadmium (5s2 4d10) inclusively. Do not forget that even the top of the diagram is lower than an unbound electron state.
An example of absorption lines in a spectrum
Graphic illustrating the formation of a Bose–Einstein condensate
Scanning tunneling microscope image showing the individual atoms making up this gold (100) surface. The surface atoms deviate from the bulk crystal structure and arrange in columns several atoms wide with pits between them (See surface reconstruction).
Periodic table showing the origin of each element. Elements from carbon up to sulfur may be made in small stars by the alpha process. Elements beyond iron are made in large stars with slow neutron capture (s-process). Elements heavier than iron may be made in neutron star mergers or supernovae after the r-process.

Chemistry is the discipline that studies these changes.

A thermite reaction using iron(III) oxide. The sparks flying outwards are globules of molten iron trailing smoke in their wake.

Chemical reaction

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Process that leads to the chemical transformation of one set of chemical substances to another.

Process that leads to the chemical transformation of one set of chemical substances to another.

A thermite reaction using iron(III) oxide. The sparks flying outwards are globules of molten iron trailing smoke in their wake.
Antoine Lavoisier developed the theory of combustion as a chemical reaction with oxygen.
As seen from the equation CH4 + 2O2 -> CO2 + 2 H2O, a coefficient of 2 must be placed before the oxygen gas on the reactants side and before the water on the products side in order for, as per the law of conservation of mass, the quantity of each element does not change during the reaction
An example of organic reaction: oxidation of ketones to esters with a peroxycarboxylic acid
Isomerization of azobenzene, induced by light (hν) or heat (Δ)
Representation of four basic chemical reactions types: synthesis, decomposition, single replacement and double replacement.
Illustration of a redox reaction
Sodium chloride is formed through the redox reaction of sodium metal and chlorine gas
Ferrocene – an iron atom sandwiched between two C5H5 ligands
Precipitation
In this Paterno–Büchi reaction, a photoexcited carbonyl group is added to an unexcited olefin, yielding an oxetane.
Schematic potential energy diagram showing the effect of a catalyst in an endothermic chemical reaction. The presence of a catalyst opens a different reaction pathway (in red) with a lower activation energy. The final result and the overall thermodynamics are the same.
Solid heterogeneous catalysts are plated on meshes in ceramic catalytic converters in order to maximize their surface area. This exhaust converter is from a Peugeot 106 S2 1100
Mechanism of electrophilic aromatic substitution
E2 elimination
Electrophilic addition of hydrogen bromide
Acid-catalyzed addition-elimination mechanism
The Cope rearrangement of 3-methyl-1,5-hexadiene
Illustration of the induced fit model of enzyme activity
Thermite reaction proceeding in railway welding. Shortly after this, the liquid iron flows into the mould around the rail gap.

Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.

Various examples of physical phenomena

Physics

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Natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force.

Natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force.

Various examples of physical phenomena
Ancient Egyptian astronomy is evident in monuments like the ceiling of Senemut's tomb from the Eighteenth Dynasty of Egypt.
Ibn al-Haytham (c. 965–c. 1040), Book of Optics Book I, [6.85], [6.86]. Book II, [3.80] describes his camera obscura experiments.
The basic way a pinhole camera works
Galileo Galilei showed a modern appreciation for the proper relationship between mathematics, theoretical physics, and experimental physics.
Sir Isaac Newton (1643–1727), whose laws of motion and universal gravitation were major milestones in classical physics
Max Planck (1858–1947), the originator of the theory of quantum mechanics
Albert Einstein (1879–1955), whose work on the photoelectric effect and the theory of relativity led to a revolution in 20th century physics
The basic domains of physics
Solvay Conference of 1927, with prominent physicists such as Albert Einstein, Werner Heisenberg, Max Planck, Hendrik Lorentz, Niels Bohr, Marie Curie, Erwin Schrödinger and Paul Dirac
This parabola-shaped lava flow illustrates the application of mathematics in physics—in this case, Galileo's law of falling bodies.
Mathematics and ontology are used in physics. Physics is used in chemistry and cosmology.
The distinction between mathematics and physics is clear-cut, but not always obvious, especially in mathematical physics.
Classical physics implemented in an acoustic engineering model of sound reflecting from an acoustic diffuser
Archimedes' screw, a simple machine for lifting
Experiment using a laser
The astronaut and Earth are both in free fall.
Lightning is an electric current.
Physics involves modeling the natural world with theory, usually quantitative. Here, the path of a particle is modeled with the mathematics of calculus to explain its behavior: the purview of the branch of physics known as mechanics.
A simulated event in the CMS detector of the Large Hadron Collider, featuring a possible appearance of the Higgs boson.
Velocity-distribution data of a gas of rubidium atoms, confirming the discovery of a new phase of matter, the Bose–Einstein condensate
The deepest visible-light image of the universe, the Hubble Ultra-Deep Field
Feynman diagram signed by R. P. Feynman.
A typical phenomenon described by physics: a magnet levitating above a superconductor demonstrates the Meissner effect.

Over much of the past two millennia, physics, chemistry, biology, and certain branches of mathematics were a part of natural philosophy, but during the Scientific Revolution in the 17th century these natural sciences emerged as unique research endeavors in their own right.

Hydrogen atomic orbitals at different energy levels. The more opaque areas are where one is most likely to find an electron at any given time.

Electron

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Subatomic particle whose electric charge is negative one elementary charge.

Subatomic particle whose electric charge is negative one elementary charge.

Hydrogen atomic orbitals at different energy levels. The more opaque areas are where one is most likely to find an electron at any given time.
A beam of electrons deflected in a circle by a magnetic field
J. J. Thomson
Robert Millikan
The Bohr model of the atom, showing states of an electron with energy quantized by the number n. An electron dropping to a lower orbit emits a photon equal to the energy difference between the orbits.
In quantum mechanics, the behavior of an electron in an atom is described by an orbital, which is a probability distribution rather than an orbit. In the figure, the shading indicates the relative probability to "find" the electron, having the energy corresponding to the given quantum numbers, at that point.
Standard Model of elementary particles. The electron (symbol e) is on the left.
Example of an antisymmetric wave function for a quantum state of two identical fermions in a 1-dimensional box. If the particles swap position, the wave function inverts its sign.
A schematic depiction of virtual electron–positron pairs appearing at random near an electron (at lower left)
A particle with charge q (at left) is moving with velocity v through a magnetic field B that is oriented toward the viewer. For an electron, q is negative so it follows a curved trajectory toward the top.
Here, Bremsstrahlung is produced by an electron e deflected by the electric field of an atomic nucleus. The energy change E2 − E1 determines the frequency f of the emitted photon.
Probability densities for the first few hydrogen atom orbitals, seen in cross-section. The energy level of a bound electron determines the orbital it occupies, and the color reflects the probability of finding the electron at a given position.
A lightning discharge consists primarily of a flow of electrons. The electric potential needed for lightning can be generated by a triboelectric effect.
Lorentz factor as a function of velocity. It starts at value 1 and goes to infinity as v approaches c.
Pair production of an electron and positron, caused by the close approach of a photon with an atomic nucleus. The lightning symbol represents an exchange of a virtual photon, thus an electric force acts. The angle between the particles is very small.
An extended air shower generated by an energetic cosmic ray striking the Earth's atmosphere
Aurorae are mostly caused by energetic electrons precipitating into the atmosphere.
During a NASA wind tunnel test, a model of the Space Shuttle is targeted by a beam of electrons, simulating the effect of ionizing gases during re-entry.

Electrons play an essential role in numerous physical phenomena, such as electricity, magnetism, chemistry and thermal conductivity, and they also participate in gravitational, electromagnetic and weak interactions.

The thermodynamicists representative of the original eight founding schools of thermodynamics. The schools with the most-lasting effect in founding the modern versions of thermodynamics are the Berlin school, particularly as established in Rudolf Clausius’s 1865 textbook The Mechanical Theory of Heat, the Vienna school, with the statistical mechanics of Ludwig Boltzmann, and the Gibbsian school at Yale University, American engineer Willard Gibbs' 1876 On the Equilibrium of Heterogeneous Substances launching chemical thermodynamics.

Thermodynamics

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Branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation.

Branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation.

The thermodynamicists representative of the original eight founding schools of thermodynamics. The schools with the most-lasting effect in founding the modern versions of thermodynamics are the Berlin school, particularly as established in Rudolf Clausius’s 1865 textbook The Mechanical Theory of Heat, the Vienna school, with the statistical mechanics of Ludwig Boltzmann, and the Gibbsian school at Yale University, American engineer Willard Gibbs' 1876 On the Equilibrium of Heterogeneous Substances launching chemical thermodynamics.
Annotated color version of the original 1824 Carnot heat engine showing the hot body (boiler), working body (system, steam), and cold body (water), the letters labeled according to the stopping points in Carnot cycle.
A diagram of a generic thermodynamic system

The results of thermodynamics are essential for other fields of physics and for chemistry, chemical engineering, corrosion engineering, aerospace engineering, mechanical engineering, cell biology, biomedical engineering, materials science, and economics, to name a few.

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Periodic table

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Tabular display of the chemical elements.

Tabular display of the chemical elements.

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3D views of some hydrogen-like atomic orbitals showing probability density and phase (g orbitals and higher are not shown)
Idealized order of shell-filling (most accurate for n  ≲ 4.)
Trend in atomic radii
Graph of first ionisation energies of the elements in electronvolts (predictions used for elements 105–118)
Trend in electron affinities
Flowing liquid mercury. Its liquid state at room temperature is a result of special relativity.
A periodic table colour-coded to show some commonly used sets of similar elements. The categories and their boundaries differ somewhat between sources. Alkali metals
 Alkaline earth metals
 Lanthanides
 Actinides
 Transition metals Other metals
 Metalloids
 Other nonmetals
 Halogens
 Noble gases
Mendeleev's 1869 periodic table
Mendeleev's 1871 periodic table
Dmitri Mendeleev
Henry Moseley
Periodic table of van den Broek
Glenn T. Seaborg
One possible form of the extended periodic table to element 172, suggested by Finnish chemist Pekka Pyykkö. Deviations from the Madelung order (8s < < 6f < 7d < 8p) begin to appear at elements 139 and 140, though for the most part it continues to hold approximately.
Otto Theodor Benfey's spiral periodic table (1964)
Iron, a metal
Sulfur, a nonmetal
Arsenic, an element often called a semi-metal or metalloid

It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of chemistry.

Hydrogen's purple glow in its plasma state, the most abundant in the universe

Matter

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Hydrogen's purple glow in its plasma state, the most abundant in the universe
Under the "quarks and leptons" definition, the elementary and composite particles made of the quarks (in purple) and leptons (in green) would be matter—while the gauge bosons (in red) would not be matter. However, interaction energy inherent to composite particles (for example, gluons involved in neutrons and protons) contribute to the mass of ordinary matter.
Quark structure of a proton: 2 up quarks and 1 down quark.
A comparison between the white dwarf IK Pegasi B (center), its A-class companion IK Pegasi A (left) and the Sun (right). This white dwarf has a surface temperature of 35,500 K.
Phase diagram for a typical substance at a fixed volume. Vertical axis is Pressure, horizontal axis is Temperature. The green line marks the freezing point (above the green line is solid, below it is liquid) and the blue line the boiling point (above it is liquid and below it is gas). So, for example, at higher T, a higher P is necessary to maintain the substance in liquid phase. At the triple point the three phases; liquid, gas and solid; can coexist. Above the critical point there is no detectable difference between the phases. The dotted line shows the anomalous behavior of water: ice melts at constant temperature with increasing pressure.
Galaxy rotation curve for the Milky Way. Vertical axis is speed of rotation about the galactic center. Horizontal axis is distance from the galactic center. The sun is marked with a yellow ball. The observed curve of speed of rotation is blue. The predicted curve based upon stellar mass and gas in the Milky Way is red. The difference is due to dark matter or perhaps a modification of the law of gravity. Scatter in observations is indicated roughly by gray bars.

In classical physics and general chemistry, matter is any substance that has mass and takes up space by having volume.

Onion (Allium) cells in different phases of the cell cycle. Growth in an 'organism' is carefully controlled by regulating the cell cycle.

Natural science

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One of the branches of science concerned with the description, understanding and prediction of natural phenomena, based on empirical evidence from observation and experimentation.

One of the branches of science concerned with the description, understanding and prediction of natural phenomena, based on empirical evidence from observation and experimentation.

Onion (Allium) cells in different phases of the cell cycle. Growth in an 'organism' is carefully controlled by regulating the cell cycle.
This structural formula for molecule caffeine shows a graphical representation of how the atoms are arranged.
The orbitals of the hydrogen atom are descriptions of the probability distributions of an electron bound to a proton. Their mathematical descriptions are standard problems in quantum mechanics, an important branch of physics.
Uncrewed and crewed spacecraft missions have been used to image distant locations within the Solar System, such as this Apollo 11 view of Daedalus crater on the far side of the Moon.
The materials paradigm represented as a tetrahedron
Aristotle's view of inheritance, as a model of the transmission of patterns of movement of the body fluids from parents to child, and of Aristotelian form from the father.
Plato (left) and Aristotle in a 1509 painting by Raphael. Plato rejected inquiry into natural philosophy as against religion, while his student, Aristotle, created a body of work on the natural world that influenced generations of scholars.
Isaac Newton is widely regarded as one of the most influential scientists of all time.
The Michelson–Morley experiment was used to disprove that light propagated through a luminiferous aether. This 19th-century concept was then superseded by Albert Einstein's special theory of relativity.

Life science is alternatively known as biology, and physical science is subdivided into branches: physics, chemistry, earth science, and astronomy.

Photons are emitted by a cyan laser beam outside, orange laser beam inside calcite and its fluorescence

Photon

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Elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force.

Elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force.

Photons are emitted by a cyan laser beam outside, orange laser beam inside calcite and its fluorescence
Photoelectric effect: the emission of electrons from a metal plate caused by light quanta – photons.
The cone shows possible values of wave 4-vector of a photon. The "time" axis gives the angular frequency (rad⋅s−1) and the "space" axis represents the angular wavenumber (rad⋅m−1). Green and indigo represent left and right polarization
Thomas Young's double-slit experiment in 1801 showed that light can act as a wave, helping to invalidate early particle theories of light.
In 1900, Maxwell's theoretical model of light as oscillating electric and magnetic fields seemed complete. However, several observations could not be explained by any wave model of electromagnetic radiation, leading to the idea that light-energy was packaged into quanta described by . Later experiments showed that these light-quanta also carry momentum and, thus, can be considered particles: The photon concept was born, leading to a deeper understanding of the electric and magnetic fields themselves.
Up to 1923, most physicists were reluctant to accept that light itself was quantized. Instead, they tried to explain photon behaviour by quantizing only matter, as in the Bohr model of the hydrogen atom (shown here). Even though these semiclassical models were only a first approximation, they were accurate for simple systems and they led to quantum mechanics.
Photons in a Mach–Zehnder interferometer exhibit wave-like interference and particle-like detection at single-photon detectors.
Stimulated emission (in which photons "clone" themselves) was predicted by Einstein in his kinetic analysis, and led to the development of the laser. Einstein's derivation inspired further developments in the quantum treatment of light, which led to the statistical interpretation of quantum mechanics.
Different electromagnetic modes (such as those depicted here) can be treated as independent simple harmonic oscillators. A photon corresponds to a unit of energy E = hν in its electromagnetic mode.

In chemistry and optical engineering, photons are usually symbolized by hν, which is the photon energy, where h is Planck constant and the Greek letter ν (nu) is the photon's frequency.

Thermal vibration of a segment of protein alpha helix. Its amplitude increases with temperature

Temperature

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Physical quantity that expresses how hot matter is, or as a measure of the average translational kinetic energy per atom or molecule in the system.

Physical quantity that expresses how hot matter is, or as a measure of the average translational kinetic energy per atom or molecule in the system.

Thermal vibration of a segment of protein alpha helix. Its amplitude increases with temperature
Average daily variation in human body temperature
Two thermometers showing temperature in Celsius and Fahrenheit
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A theoretical understanding of temperature in a hard-sphere model of a gas can be obtained from the Kinetic theory.
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Temperature is important in all fields of natural science, including physics, chemistry, Earth science, astronomy, medicine, biology, ecology, material science, metallurgy, mechanical engineering and geography as well as most aspects of daily life.